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Unformatted text preview: allylic carbocations Least sterically hindered 3’ alcohol Benzyl alch Allylic alch 2’ Adds Cl 1’ alcohol aldehyde COOH 2’ alcohol ketone ONLY aldehydes ONLY aldehy des and ketones Stable enols & phenols Aldehydes and ketones w/ alpha-hydrogen can form enols Notes Racemic mixture if stereocenter Inverted answer 1’ halides NR Phenols NR 3’ alcohols NR Bromine is anti addition Carbonyl compounds others than aldehydes NR No other carbon yl groups (ester, amides, COOH = NR) Corrosive Poison Flammable Lachrymator Carcinogen Explosive Irritant Phosphoric Acid (H3PO4) Cyclohexane Allyl Halide 2,4- DNP Tollens Reagent Trans-cinnamic Acid Hydrochloric Acid (HCl) Cyclohexene Benzyl Halide Chromic Acid (CrH2O4) Ethanol Sulfuric Acid (H2SO4) Ethyl acetate Bromine Hexane Iodine Isopropyl Alcohol Acetic Acid Xylene...
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This note was uploaded on 03/31/2009 for the course CHEM 2364 taught by Professor Davila during the Spring '08 term at LSU.
- Spring '08
- Organic chemistry