Assign 6-2 - Organic Chemistry Assignment 6-2 1. Indicate...

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Organic Chemistry Assignment 6-2 1. Indicate the most reactive substrate in S N 1 reactions 2. Indicate the most reactive substrate in S N 2 reactions 3. Indicate the most reactive substrate in S N 1 reactions 4. Indicate the most reactive substrate in S N 2 reactions 5. For each of the following, indicate the more/most reactive nucleophile (Explain your answer) A. CH 3 -NH 2 vs. CH 3 -NH .. .. .. .. B. OH : .. .. vs. F : : : .. (in DMSO solvent) C. H 2 Se .. .. : : .. .. : .. F : : .. .. Cl : : .. .. Br : .. .. I : .. : H 2 O H 2 S E. , , , , , (in DMSO solvent) D. (in CH 3 OH solvent) : .. F : : .. .. Cl : : .. .. Br : .. .. I : .. : , , , Note: DMSO is an apropic solvent; CH 3 OH is a protic solvent 6. Why does t-butyl iodide (2-methyl-2-iodopropane) react faster than ethyl iodide (1-iodoethane) in S N 1 reactions? 7. Why does ethyl iodide (1-iodoethane) react faster than t-butyl iodide (2-methyl-2-iodopropane) in S N 2 reactions? CH
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This note was uploaded on 04/07/2009 for the course CHE 311 taught by Professor Drake during the Fall '08 term at American International.

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Assign 6-2 - Organic Chemistry Assignment 6-2 1. Indicate...

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