Assign 8-3 - Chapter 8 Problem Set 3 1 Give the organic...

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Chapter 8 Problem Set 3 1. Give the organic product(s). Draw 3D formula(s) where appropriate CH 2 C CH 3 CH 3 C C CH 3 CH 3 CH 3 CH 2 H + KMnO 4 (aq) H 2 O / OH - 25 o C 1) O 3 1) KMnO 4 / OH - heat H+(aq) 1) O 3 2) Zn/ H 2 O 1) O 3 CH 2 CH 3 2) Zn/ H 2 O 2) CH 3 -S-CH 3 CH 2 CH 2 + KMnO 4 (aq) H 2 O/ OH - 25 o C CH 3 -CH 2 -CH CH 2 + OsO 4 , H 2 O 2 + OsO 4 , H 2 O 2 CH 3 -CH 2 -CH CH 2 + C 6 H 5 -CO 3 H CH 2 CH 3 + CH 3 -CO 3 H A. B. C. D. E. F. G. H. I. J.
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2. What alkene yields each set of ozonolysis/ reduction products? (a) (CH 3 ) 2 C O + (CH 3 CH 2 ) 2 C=O (b) O CH 3 CH 2 CH O + (c) CH 3 C CH 3 O only 3. Compound X has the molecular formula, C 8 H 12 . In an addition reaction, one mole of X absorbs 2 moles of H 2 (g) in the presence of a Pt catalyst to form a compound Y, C 8 H 16 . Ozonolysis/ reduction produces only one product, butanedial, shown below. Deduce the structure of X and of Y
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Assign 8-3 - Chapter 8 Problem Set 3 1 Give the organic...

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