Assign 11-1 - SOCl 2 HCl ZnCl 2 N(CH 3 3 PBr 3 CH 3 CH 2 CH...

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Organic Chemistry Assignment 11-1 1. Give the organic product(s) formed in each reaction below: A. OH + B. OH + C. + C CH 3 CH 3 OH + D. E. + OH F. + P + I 2 G. OH + H. + OH 2. Give the mechanism expected for reactions 1 A and 1 B above (indicate slow step) CH CH 3 CH CH 3 OH OH SO 2 O I. CH 2 OTs + Na + - OC 2 H 5 J. CH 3 CH 2 CH 2 O S O O CH 3 + CH 3 -NH 2 .. Note: OTs = CH 3 O S O O CH 3 CH 2 CH 2 HBr CH 3 -CH-CH 3 HI CH 3
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Unformatted text preview: SOCl 2 HCl ZnCl 2 * N(CH 3 ) 3 PBr 3 CH 3 CH 2 CH 2 CH 3 HI Cl Hint: Reactions I and J, both -OTs and O S O O CH 3 are both good leaving groups in nucleophilic substitution reactions. *ZnCl 2 is a helper catalyst required when HCl reacts with alcohols...
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This note was uploaded on 04/07/2009 for the course CHE 311 taught by Professor Drake during the Fall '08 term at American International.

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Assign 11-1 - SOCl 2 HCl ZnCl 2 N(CH 3 3 PBr 3 CH 3 CH 2 CH...

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