Assign 17-5 arene side chain reactions

Assign 17-5 arene side chain reactions - radical when a Br...

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ASSIGNMENT 17–5 (Reactions at the side chain of arenes) a CH 2 CH 2 CH 3 + light b. + HBr CH + HBr CH c. CH 3 d. CH + CH CH 3 e. + CH f. CH + NaOH CH 3 g. + H 2 SO 4 h. + KMnO 4 /OH - i. + K 2 Cr 2 O 7 / H + heat heat CH 2 CH CH 3 Cl Predict the organic product(s) 1. CH 2 CH CH 3 OH CH 2 CH 2 CH 3 CH 3 CH 2 CH 3 ROOR H 2 O H + H 2 O H + H + N-Br O O Hint: Recall HBr addition to alkenes when peroxides are present. Which is the more stable
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Unformatted text preview: radical when a Br atom bonds to an alkene C, in this molecule ? a CH-CH 2 CH 3 b. CH-CH 2 CH 3 c. d. e. f. i. CO 2 H CH 3 CH 2 CH 3 ANSWERS Br Br CH 2-CH-CH 3 Br CH-CH 2 CH 3 OH OH CH CH CH 3 CH CH CH 3 g. h....
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This note was uploaded on 04/07/2009 for the course CHE 312 taught by Professor Drake during the Spring '08 term at American International.

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Assign 17-5 arene side chain reactions - radical when a Br...

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