EXAM_2_CHE3332_S2004

EXAM_2_CHE3332_S2004 - 1 Give the major product(CH3)3C-Cl 1...

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1) Give the major product. (CH 3 ) 3 C-Cl 1) Mg o , ether 2) HBr A. (CH 3 ) 3 C-Br B. (CH 3 ) 3 C-H C. (CH 3 ) 3 C-OH D. (CH 3 ) 2 C=CH 2 2) Which compound does NOT give a tertiary alcohol upon reaction with methylmagnesium bromide? A. 3-methylpentanal B. ethyl benzoate C. 4,4-dimethylcyclohexanone D. 4-heptanone 3) Which compound gives a secondary alcohol upon reaction with methylmagnesium bromide? Assume the usual acid workup. A. butyl formate B. 3-pentanone C. pentanal D. methyl butanoate 4) What is the major product of the reaction? O O 1. MeMgBr, Et 2 O 2. H 3 O + , H 2 O ? A. OH OH achiral B. O OH racemic mixture C. O OH racemic mixture D. O OMe racemic mixture 5) What is the major product of the reaction? [PARA]
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O Optically active 1 EtMgBr, Et 2 O 2. H 2 O, H 3 O + A. Et OH + Et OH B. Et OH + OH Et C. Et Et OH OH + D. OEt + OEt 6) What is the major product of the following synthesis? [PARA] Cl 1. Mg, Et 2 O 2. 3. NH
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This note was uploaded on 04/30/2008 for the course CHE 3332 taught by Professor Primrose during the Spring '08 term at Baylor.

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EXAM_2_CHE3332_S2004 - 1 Give the major product(CH3)3C-Cl 1...

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