Week_2.3_PurpleBook_Answers

Week_2.3_PurpleBook_Answers - 52 Chirality Week 2 1 For...

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CH 3 H 3 H H H 3 C Cl F Br Br H H Br H H Br 3 H 3 C 3 H 3 C H 3 C H Chirality H 3 F 1. For each of the following species, indicate if it is chiral or achiral . For those molecules that are chiral, circle all stereocenters, and draw the structure of the enantiomer. chiral chiral Br Br H H achiral chiral achiral ("meso") chiral H 3 C CH 3 H 3 C CH 3 Week 2 52
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H H H Cl O N HO H 3 C OH H 2. Draw an unambiguous structural representation of the following molecules: R and S Nomenclature 1. Circle all the stereocenters in the following molecules. For each stereocenter, assign an R or S designation according to the standard rules. ( S )-4,5-dimethyl-( Z )-2-hexene H R R R S S S R S S ( R )-3,5,6-trimethyl-( E )-3-heptene H 3. Provide the best possible systematic name for the following compound: (S)-(E)-5-isopropyl-2,3,7-trimethyl-4-octene Week 2 53
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CH 3 CH 3 H 3 C 3 Br Br H 3 C Br Br 3 Enantiomers and Diastereomers 1. For each of the following pairs of stereoisomers, indicate if they are enantiomers, diastereomers, or identical compounds. diastereomers diastereomers identical enantiomers identical Week 2 54
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Identifying Isomers H H 1. For each of the following pairs of isomers, indicate whether they are Identical, Enantiomers,
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Week_2.3_PurpleBook_Answers - 52 Chirality Week 2 1 For...

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