322b--exam 3 %28sp.1998%29 - -1 Ch~roistry 322bL,32SbL.Exam...

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-1-'- . ""'. . . . '. . . Ch~roistry 322bL,32SbL . . -2- '.Exam No.3' .' '. . '. ," , . . (1) (3Q).. 6~ritplete ~e ~a~tio~bel()w by supplyU;g the IItisSiI\g ~a~taI\t pr product "',i~ide eachbox.Becar~fJlltoindicate all major .organicprocfucts when more than " . pne is form,ed. . It is not necessary to give the byproducts of,the reaction. Be careful . '. .to showste.reqC:hemical details wherever tha yare important. "Workup" means' }reaqnentwifu'liarerand brInging the solutio~ \0 neutral pH. .. ... .. . . .' .' .Cf? ".". '. . '..' '." . 1-1 H C>, . . O CH ..0. . d ' n HO " /H O . '. .11 '" .'" '" .' '.' n . .' . ..1. @J G:'C- ~q.I.3 '/ . + CH3CCH3. 0 . .," '.""'/. '. ..' .heat J V C1oHIQO ~ IS .-. .Name~ ~ ~ CH3COCCH3 C ~ o r I ..h'O ~ Na+ '. .' ." '..' -+ '(i-Pr)2N Li ". ""'. . ,ethyl ethet . (CH3hSiCJ
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. . . . . .. . . ...Che~stry322bL/32SbL. . Exam No.3 .. . . .. Contd. ~ >(G) . . . <r? . ~ . . ... . .CHjCH2OCCH2COCH2CH3 -3- . .. . Name-1l1~n~ . heat .. . . . . . . . . . .. 11' . <rf ... . . CH3CCH2COC2~ . .. + - .. (i) Na OC2Hs : :~ (ll) Workup .(ii) ~
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~ .. . . .. ... . 0 .. ~ CH2<;:HCH2CH3 1 COCl ~ (i) AlCl3 (ii) Workup .1,t'a.. Zn.Hg HCI /5 . . Name (hc ~"e.s + - .. (i) Na OC2HS (ii) CH3CH1Br (i) HO-, H2O: - (ii) H30+ heat (Hi) C . ">(JZo . h~/ i\ a H+
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try 322bL, 325bLI I fo.3 . Answer the following questions.. Provide. proper names, !UP AC or CH3CH2~HCOOH .. . CH3 _. .. . . . 2-me,4kybv.~t\Oi~qt.<.J . .{" , , , " , ' , ' ': ,(3) (15) ',", «A) (6) , , ~ , . ..
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