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Unformatted text preview: indicate "no rxn" () 8. c. 5 4 3 2 1 g. CHsCH::CHCH=CH2 + HBr .. light or +Br2 ~ ROOR h j. +HCI ,. + 8. Synthesize from alcohols of 4 carbons or less as the only carbon source and any other needed reagenl (C~)sC-CH:lCH(C~)2 8. t-BuOH + PBr3 (:=J t-BuBr + Li metal (:::=:::J b. KMnO4 ,.. NO RXN cold 0-r+CtbMgBr - ~ d. 1 )Na8H4 ~ 2)HP 0+&2 ,. CCl4 ~ hv--. . CCI4 Endo-isomer No R><n. ~o + + (t-Bu)~uLi + BrCH:PH(CHs~ il c=) t.. .0. 2#Uu + Cui HOCH2CH(CH:Y2 + PBrs 2. I b. Synthesize ~H (:::J~Br (::::=J /'VMgB~ Y .. -. .. + MgJEt~ HaO+~ 9.Indicate which of the following is (A) aromatic (B) anti-aromatic (C) non-aromatic + . OOOOQQ (A) (0) (0) (A) , L~H~ b. ~~r' 1 . ~ NBS""" Br . : ;c,,::' . w...~m!q, starting with alcohols of 3 carbons or less as the only carbon source and any other needed reagents ~ QQ ('ar-t), + + . +Br + / 1...
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This note was uploaded on 03/02/2008 for the course CHEM 322BL taught by Professor Singer during the Fall '07 term at USC.
- Fall '07
- Organic chemistry