FOR FINAL - CHAPTER 13 Infrared Spectroscopy (IR) 13.1...

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CHAPTER 13 – Infrared Spectroscopy (IR) H 13.1 – Electromagnetic Radiation (501) 3 13.2 – Interaction of Electromagnetic Radiation with Molecules (502) 3 13.3 – The Electromagnetic Spectrum (503) 3 13.4 – Infrared Spectroscopy (505) 3 13.5 – Generalizations (507) 1.) Because of their larger force constants, stronger bonds absorb at higher wavenumbers than weaker bonds. 2.) For similar reasons, bond stretches absorb at higher wavenumbers than bends 3.) Bonds involving a light hydrogen atom have smaller reduced masses and therefore absorb at higher wavenumbers than bonds involving only heavier atoms. 3 13.6 –The Hydrogen Region (508) 3 13.7 – The Triple-Bond Region (515) 3 13.8 – The Double-Bond Region (518) 3 13.9 – The Fingerprint Region (520) 3 13.10 – Interpretation of IR Spectra (521) CHAPTER 14 – Nuclear Magnetic Resonance Spectroscopy (NMR) H 14.1 – Proton Magnetic Resonance Spectroscopy (543) 3 14.2 – Theory of 1 H-NMR (545) 3 14.3 – The Chemical Shift (547) 3 14. 4 – Spin Coupling (556) 3 14. 5 – Complex Coupling (562) 3 14.6 – Chemical Exchange (563) 3 14.7 – Deuterium (563) 3 14.8 – Interpretation of 1 H-NMR Spectra (566) 3 14.9 – Carbon-13 Magnetic Resonance Spectroscopy
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This note was uploaded on 05/04/2008 for the course CHM 228 taught by Professor Rosen during the Spring '08 term at Rhode Island.

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FOR FINAL - CHAPTER 13 Infrared Spectroscopy (IR) 13.1...

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