9_2536_06_T2a - Test 2 Name_ O Chem 2536 Pledge: I have...

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Test 2 Name________________________________________ O Chem 2536 Pledge: I have neither given nor received information on this test. Spring 2006 _________________________________ Table of Some Reagents 1) KMnO 4 2) H 3 O + 1) Zn(Hg), HCl 2) OH SOCl 2 MnO 2 NBS, , ROOR 1) Provide the mechanism and product for the acyl substitution shown below. Label the electrophile, nucleophile, and leaving group. (8 pt) 2) Rank the following carbonyl carbons from most reactive (1) to least reactive (4) towards a nucleophile. (8 pts) C H 3 O O CH 3 C H 3 CH 3 O CH 3 O NH Cl C H 3 O NH CH 3 ________ ________ ________ 1
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3) Propose a mechanism to show the formation of the following product from the given reagents. (9 pt) 4) Give the following compounds IUPAC names: a. _________________________________________ b. __________________________________________ 2
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5) Match the term with one correct structure. There may be more than one correct structure and structures may be used more than once or not at all. (2 pts each)
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9_2536_06_T2a - Test 2 Name_ O Chem 2536 Pledge: I have...

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