Chem 51A F07 EXAM - amp primal wait ml W E y 105M W Peat...

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Unformatted text preview: amp) primal wait ml W. E y 105M \ , W Peat NLMWIOULW C MEN 5" g SANJ'yo-r SANGodkc You have 1 hour to complete this exam. Make sure to include formal charges and lone pair electrons when necessary! \ Draw at“. for the following molecules. a. O \J. ‘ao. -‘O I. xm / ,, , / W 'O\ N” o \5‘ b. HC02CH3 -u ‘ 10': l“ by H x I‘ ll 1 \ 4 L.” C." U 0 ”ll % i_( H/ \O/ 3‘3 \4 f g. Draw the skeletal structure for the following compounds I l” Chloo' El" “WP 77 lt’lftllwl (.jclchfxmxtc (A K b. 4-ethyl-2-fluoro-4-methylheptane b MOM”C -, . N {LL )7 4““ 0t“? C30 {1) wfldx h‘leli’llanfi wmv pr>nwm, «quemaw (x Name the following compounds using the IUPAC system CH3 “JV.“ [I ",1 XL ram mummy {um-um 5qu Cunnafiwfij are dflt’wm” 3 \L How maybe possible for C3H6BrCl‘? Draw them all. N M /((\\/9r m ‘ \ 6r 1'- 1 .‘L\ -- .. -- ' .61 “(4.0. v. 1: ”:31" a: 0—6—9 10:: »—0‘\ ' \3‘ «>1 . /‘l H U". f- N 1‘ “if 6. / ‘H b— L ( I \ f C 4? C ;' j/ ‘sp' Hp: “P h “111: 71.1211 111:111 represcnnnnns h1rthree <t1ggertd u1111'11r1111-1I'11111x 111' "3- -11111h_1.| 111111111 1. 111111115: 11111111 1111. t ‘ (.71i111r1d1£2111111111!) «flange {he confirmation: 1! m men 1111111: 111111 hei11\\-.fr11m 11111111 111:1. '.1!1: {11 fem-.1 11111.11: It 21111 are s 111111] 1. 1111115111 - 511111. ' .. Mum l - WWW ( audit W H4” r We 1/ ‘ s h 0”“wa dagows 2' w“ / o i’ NH3 CH30H NH4 cngcou cn4 gtuw was: F G H J K imt (10 0“ I (3m &.%ich compound is the least acidic? \wmch compound is the mos! acidic? .33” O Q Which compound has the strongest conjugaxe base?- } 9. {l \Oomrwfl (on (EH3 Mam-hm? 4/ CH3OCH2CH20H CH3CH20CH2CH3 Homzcnzcnzoa H- (2—0013 guyfimg arm F G H '04; J l or? 3) Which compound would have the highest boiling point?- & Which compound would have the lowest boiling point? e; Which compound would be the most water soluble? L—) H’ homing 10. Label each of the following compounds as “insoluble” or “soluble” in water. as . ,fi W/ '. _.._O “‘H‘ 1"“ . :i: ’ V ' .. U. i d a ‘ LE 7 i m \U W: lflSbluw AW \ l“ Lilli/"E a C \&I( N + \.I ”PU I"'—"“_‘. PHI W} ~1I(\ \‘A\.IEI('U + NILE WHCI‘O + \Dlimm ¢I\\\I{‘ II 9,0 ‘ AK ”8% I'VMMWM f" 11. Hui acidrbasc equilibria arr: ahuwn helnw. in each t‘qunrmn the two reI’lL‘lI'lan un IIII‘ Icn \lth.‘ III Ihc tqtiiiihrlum are dcsignulml A & B The awn) magnum UH Ihe ugh: are dcsignutcd (I 65; I}. In the fifth equatmn. lift“). is. I‘L‘EIL‘lil-I‘JI {T and NIL I5 D. 3430 1:;an IIII'I'I prudut‘i. A Inhic {If pk. IIIiuers I: pruvIIIfd at the bImnm III (in: pugs. For each chIIIIbI'iLIm. three quvslinux me pmcd I. Which reactants function as Brvnslm! ”mix" ITIIII Ecru-Is IA II'IIIIIIuh DI Ishuuld in I-IIIcrcd III I11:- dl'IF-HIV-‘Sr hm; ! Whlch rczu'IIIIII H the :tI'IIIIgCI base 5’ {One leIIEI = A through D) muuld I»: uIIIcIcII III III: ans“ er buxl I \K'h'IL-II sad: m The chIIIIbrIum II. III\HI”L'I1‘1IIIEftUY right sshnuid h? cmercd In the .‘ithL‘T [my] IfaJ "mm-“ T‘ \\ laid} I ‘w‘u'hII'II is. \K huh «II-III: H dLI IIs‘ 1hr? I» IEHIII‘I-II' RI'JUIHH -\ + RemIImI 8 ‘RC' IIHLIIIIIN ~ Rcaunu D :u‘ MK‘ \Irnn- 't‘! WWII ,, ,, . . .. ......... . ...__.____4__.____A my ‘ . ,I ‘ 1 LINE" Eh" 1,’ am: I FUR" j: ’I‘.‘ In 1| {11: r‘Hf” r=-.vi',-f I . @ “7* / #w’r .II HIIIUH I .\I210H ‘LlfitIHLIEU ‘ ’IIIIU ”N D E‘ U MRI/“H 0* ““519 “9 . III +(‘H I‘IINII 1——- \III ICIIILUIH Io mm» 1 i ' I? ' \IISIH-(C‘HJHHI {Vivi-L5» CHIEWJI 9J9 A V ; p-r—"_-— _ M I, I _ h I. filIIflIIfiflN ’ .-\.I.i HI: ”‘1' II‘I’U. H:- IIIIIIII HIIII1 HA \‘II II \ I.II.IJII III-‘III'H I-iHIIE‘I-H . ".2 - " I). _ (Y WW M“ WW“ _ IA Q5 ...
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