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Bidirectional Searching in Synthetic Simplification

Bidirectional Searching in Synthetic Simplification - Shair...

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Shair Chem 215 Lecture 3: Bidirectional Searching in Synthetic Simplification Monday, September 24, 2007 Reading Assignment: Corey & Cheng Ch 5-6; Handouts: Oxidation, Protective Groups, and Birch Reduction; SANROS pp 154-155, 164-165, 354-355, 470-471 Partial List of Topics Discussed: Bidirectional Searching in Synthetic Simplification, Substructure Matching, Identifying and Clearing Obstacles to Implementing Powerfully Simplifying Transforms in Synthetic Problem Solving. Partial List of Transforms Covered: Aldol, Aldol-Dehydration Alkylation of α -Formylated Ketones Sulfur Ylide Epoxidation Carbonyl Homologation Reactions Quinone Diels-Alder Reaction Fischer Indole Synthesis Beckmann Rearrangement Reduction of Enediones to Diones Olefin Epoxidation Reductive Epoxide Opening Hydroboration/Oxidation Oxidative Coupling
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