lecture 12. 2

lecture 12. 2 - Corey, E. J.; Desai, M. J.; Engler, T. A....

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N OH O Me H Me O OMe Me O Me Me O OH CO 2 H Me Me H Me H Me H Me OH OH OH O OH OH OH O Shair Chem 215 Lecture 12: Stereochemical Strategies: Classical Approaches to Stereochemical Problems Wednesday, October 31, 2007 Reading Assignment: "Substrate-Directable Chemical Reactions" Hoveda, A. H.; Evans, D. A.; Fu, G. C. Chem. Rev. 1993 , 93 , 1307-1370. SANROS pp 220-223, 336-337, 368-369, 406-411. Syntheses Discussed: References: (±)-Indolizomycin: Kim, G.; Chu-Moyer, M. Y.; Danishefsky, S. J.; Schulte, G. K. J. Am. Chem. Soc. 1993 , 115 , 30-39. (±)-Ovalicin: Corey, E. J.; Dittami, J. P. 1985 , 107 , 256-257. (±)-Retigeranic Acid:
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Unformatted text preview: Corey, E. J.; Desai, M. J.; Engler, T. A. 1985 , , 4339-4341. Graphical Transform Guide: Partial List of Transforms Covered: Heteroatom-Directed Epoxidation of Olefins with m-CPBA Heteroatom-Directed Epoxidation of Olefins with VO(acac) 2 Heteroatom-Directed Cyclopropanation of Olefins with Simmons-Smith Reagent Heteroatom-Directed Hydrogenation of Olefins with Cationic Transition Metal Complexes ()-Indolizomycin ()-Ovalicin ()-Retigeranic Acid...
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