Exam 4 p3 - 02{4 a Q‘l'Whfi-Fidtg 6313.“{award EC”...

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Unformatted text preview: 02. {4 a. Q‘l'Whfi-Fidtg 6313.“? {award EC” while, “19 (‘5 o. warts—grate! . ‘ . . . 2“?“ a i-biuisln (b) (i) What is the reason for the color difference between arterial blood and venou lood? Hut Tine, "gix’rk Lounniwxb‘oa 931 $5 Nautical l); L0 In VErwus blood L3fli¢olly>l while, in mlen‘aQ (“33‘9“ 4-265 Howl] V 0 Radio’sjflamfed blood 4950:“ green, bul’ k [A M ‘ a Jul [@4143 {a reader “Lspr kw. Moves l’o eower oer lnpi‘rms * a C C 1‘ t) 33¢“ 3+ _ A_-or§.fal adii’l’l‘hfl‘ F) Ga? 0U: “a? Meal“ PIC! EIE‘MJIHJ‘ rf‘ghie5 01 10. (D The Co(NH3)6 ion is diamagnetic, but Fe(H20)6 is paramagnetic. xplain. ' Tie»; we. Lou. one rows 1,qu ALE +3 tinge .1; 06m.) , _ 11 and H»: stronger Ffelol ligmcl, NH, , prance, a, larger tffisfo“ slide. sfmhgfllw 414.4. 11. (2) Is the d—orbital splitting greater in Octahedral or Tetrahedral complexes? Why? in octahedral Cemeifixe g) laemusc 'i'lael‘e :5 a Teal?“ ”welfare“? 9“ H“ pro-similar of, (Le, rePalerv-e (laud field ‘l’o He lug flees OF orbitals 193 am! 61%" 12. (a) ( 1) As the two ligands along the z—axis of an Octahedral complex are removed, what happens to the energy of the dzz orbital as compared with the energy of the dx2.y2 orbital? it: A¢Or¢q5¢$ Iv~ zmgrfi 57kt: l‘l’ is he (onser ngn’f’g‘i olfrgdjj q‘b 0mg HA6 Qigmls 41an +6.; 7. axis. Tine- 5M1! Jamil-stupecl n}: 5.3“ Foin‘i’i «it He. other s 24 , la ‘ ' K‘ W (b) (1) With the axes defined as in (a), what are the two highest energy metal d OFbltalc‘Swlflqe r L 3 P ) a square planar complex? cl “'1" > cl ‘3 Tim» In er x—S Plane] avatar] file one Pghfiuj alirea+l7 4" lb: lisrwlsn 13. (1) Why are elevated temperatures necessary to initiate fusion reactions but not fission reactions? Far ‘l’wo posil'iuzlj charrjcci “UN—i=3 i'b £05; , (43“ “erflj “Junk“ are fleccflu‘j iv werWQ rgaksme {eras . 1:234 H‘ “arm“ :5 shaman] neutroré so {-Lart i’be acmein‘on awn-3'1 (gar :13 absarFHa“ i: MucLi lower- !Jeulfan absa'fab‘on lunls l" 4“ 14. (I) Write balanced equations for the following nuclear decay proceis‘swei’siui‘l‘2 “Mia‘s "‘ “rt?“ “5&5 ‘ (a) Chromium-51 (atomic No. 24) -- Electron capture 5'1 5'! ‘ ‘ O 1HC( + C ._._) 13 --1 (O (b) Iodine-131 (atomic No. 53) -- Beta particle emission (3(1 ‘__> o e + I’the g ’5 ‘ l :1 (t) (c) Copper—62 (atomic No. 2‘1) -- Positron emission £1 . O 67— _ ——> e + 1? Cu H 13”“ (I) (d) Uranium-235 (atomic No. 92) -- Alpha particle emission (initially) 135’. H “—31 + gnu —-> mite qa’l—k 15. (7.) How does the Neutron/Proton ratio change in each of the following processes? (a) Beta-particle emission (b) Positron emission (0) Electron capture (d) Alpha-particle emission. Decrease lkc(ec4¢ lucraqs: (Mag-case. AA 0 o o "1 A7. +1 —l -i -9- ...
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