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Test_1b_soln_update - Test lb Name 0 Chem 25.36 Pledge l...

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Unformatted text preview: Test lb Name 0 Chem 25.36 Pledge: l have neither given nor :‘eeeived information on this test 8131ng .2006 Table of Some Reaeents 1) KMnO4 2) H30+ 1) 211(Hg), HCl 2) “OH NBS, A, ROOR MnOg NHNOg, l—lCl1 0°C i) Provide the electropliilie aromatic substitution mechanism for the reaction below. include the mechanism for the formation of the eieett‘ophile (use 2 eq of l~12804). Use arrows to Show electron movement. Provide resonance structures and the resonance hybrid for the intermediate. Label the uueleopiiile, electrophiie. and rate determining step. e ‘2 ers' \ N u ‘- m «m 9 a. \fi 4’03“ 3......» E; ‘5 2) Circle the aromatic compounds. m Z; §¥rbu~5 8) a. From the given structures. circle the compound that corresponds to the infrared spectrum a For the infrared spectrum, label the absorptions indicated in the blanks provided 9\ CH OH /_... 3 N \ H30 CH3 -.‘| 2‘“ l' , : ‘ 7 f . \ i _ i f ‘ f g 1 , 12‘ l I i i I ; , g: l :1 l 3 i I. , i I I , . H i f. i E 1 4.5L E ; I r ‘ I '2 5 if; 1 I I I f- D 34 30 3000 2000 I790 W00 ancnumbezs (c M) O x it cos “533*: CA“ AU P I'L'A’ir Cw C“ l—\ C: 0 EVA? AL C,.o r1 0 L.“ 9) Give the major organic product(s) of the foilowing reactions. 3. \i K . \ i402 -————a-~ / i H0 HNO3 ‘4 0 DIP + Nb: /N\ o \o *- E» 4— 800 gp’rg Ux {17% U: ...
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