CH19 April 14 - Ester Formation: Aminolysis: Title: Page %d...

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Reactions of Acyl Halides (cont'd) Reductive Alkylation using Grignard Reagents: Examples: Formation of Ketones using Gilman Reagents: Example: Produces a 3 oalcohol and goes through a ketone intermediate that is difficult/impossible to isolate Acid chloride + diorganocopper reagent Title: Page %d of %d
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Preparation of Acid Anhydrides: Example: Reaction Mechanism: Carboxylate + acid chloride Why do you use ether and not H 2O as the solvent? Title: Page %d of %d
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Reactions of Acid Anhydrides Reaction Summary: Show comparable chemistry to acid halides Slightly less reactive (see chart) Title: Page %d of %d
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Reactions of Acid Anhydrides Preparing Commercially Valuable Acetate Esters
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Unformatted text preview: Ester Formation: Aminolysis: Title: Page %d of %d Preparation of Esters: Reaction Summary: Title: Page %d of %d Acyclic and Cyclic Esters: Reactions of Esters Hydrolysis: Title: Page %d of %d Reactions of Esters (cont'd) Hydrolysis: Base Catalyzed Mechanism Title: Page %d of %d Hydrolysis: Acid Catalyzed Mechanism Reactions of Esters (cont'd) Title: Page %d of %d Aminolysis: Reactions of Esters (cont'd) Reduction: Not often used in preference to acid chloride formation of amides LiAlH4produces 1 oalcohols DIBAH (aka DIBAL) produces aldehydes Mechanism: Title: Page %d of %d...
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This note was uploaded on 05/08/2008 for the course CHEM 2212 taught by Professor Habbard during the Spring '08 term at University of Georgia Athens.

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CH19 April 14 - Ester Formation: Aminolysis: Title: Page %d...

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