Formula_final - Integrated Rate Laws and Fundamental Kinetic Relationships 1 1 1 Second Order = kt t 1/2 =[A]t[A]0 k[A]0 First Order[A]t = kt

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Integrated Rate Laws and Fundamental Kinetic Relationships Second Order: 1 [A] kt + 1 [A] t 1 k[A] t0 1/2 0 == First Order: ln [A] [A] kt t 0.693 k t 0 1/2 =− = Zeroth Order: [A] kt [A] t [A] 2k 1 / 2 0 =− + = = 1 2 1 2 1 1 ln T T R E k k a RT E a Ae k = Fundamental Equilibrium Relationships ( X = H + , OH , K a , K b , K w , etc.) () K=K RT pc n Fundamental Thermodynamic Relationships ∆∆ G H T S =− G H T S °= °− ° G = R TK ° − ln ∆ ∆ G= G +RT Q ° ln G nFE G nFE °= − ° E = E RT nF Q °− ln E= n K ° 0 0592 . log it = n F N ⋅⋅ E = RT nF K ° E = E
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This note was uploaded on 05/06/2008 for the course PE 123 taught by Professor Bla during the Spring '08 term at Clarkson University .

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