final2007

final2007 - C. F. Bernasconi Final Exam March 19, 2007...

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C. F. Bernasconi Chemistry 108A Winter 2007 Final Exam – March 19, 2007 This exam consists of eight (8) questions for a total of 150 points. Try to answer all questions. Write your answers in a Blue Book. Put your name and that of your TA on the cover page. 1. ( 40 points ) Show the major organic products of the following reactions (no mechanisms). Indicate the stereochemistry where relevant. Note that in some cases there may be no reaction. (a) + Br 2 ? (b) CH 2 CH C CH 2 CH 3 + HOC C C COH O O ? (c) C HO O + (CH 3 ) 2 CHCl AlCl 3 ? (d) CH 3 + SO 3 conc. H 2 SO 4 ? (e) CH 3 CH 3 CH 3 + Mg ether ? (f) CH 3 CH CH CHCl CH 3 S-form ? CH 3 OH (g) C HO O + HNO 3 H 2 SO 4 ?
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C. F. Bernasconi Chemistry 108A Winter 2007 Final Exam March 19, 2007 Page 2 CH 2 CH 3 (h) ? BH 3 THF H 2 O 2 NaOH C C CH 3 CH 3 H H CHCl 3 NaOH ? (i) O 3 ? (j) 2. ( 8 points ) Assign R/S configurations to the following molecules. (a)
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final2007 - C. F. Bernasconi Final Exam March 19, 2007...

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