Handout5_Chapter14 - Chemistry 008 Dr Neal Abrams brought...

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Chemistry 008 Handout #5 Dr. Neal Abrams brought to you by the Spring 2007 Learning Strategies Center NOTE: This review sheet is for Chem 008 attendees and is to be used in conjunction with lecture notes, handouts, problem sets, the textbook, the laboratory manual, and notes from Chem 008. Chapters 14 Review Guide Lectures 2/20 and 2/22 I. Reaction Mechanisms: a. If relative rates of each step are known, i. Write the rate law for the slow step ii. Assume the rates of the forward and reverse reactions are equal for each of the fast, reversible steps. iii. Set the rate law expressions for the forward and reverse reactions of each of the fast reversible steps equal to each other. iv. Solve for the concentrations of any intermediates in terms of the rate constants and the concentrations of the reactants. v. Substitute for the concentrations of intermediates in you original rate law expression. b.
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This note was uploaded on 05/18/2008 for the course CHEM 2080 taught by Professor Davis,f during the Spring '07 term at Cornell.

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