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Unformatted text preview: ] A [ k ] A [ k dt ] A [ d 1 = = Integrated Rate Law: kt ] A ln[ ] A ln[ t = Second Order Reaction: Rate = 2 ] A [ k dt ] A [ d = Integrated Rate Law: kt ] A [ 1 ] A [ 1 t + = Spontaneity and Electrochemistry: For Reversible Process: T q S rev = eq o cell K ln n V 025693 . E = Gibbs Free Energy: G = H -T S 1 Ampere = 1 Coulomb/second 1 Faraday = 96,485C/mole = charge on 1 mole of electrons 1 Volt = 1 Joule/Coulomb G = G o + RT lnQ o cell o nFE K ln RT G = = Nernst Equation: Q log n V 0592 . E E o cell cell = ) cell half . oxid ( E ) cell half . red ( E ) anode ( E ) cathode ( E E o o o o o cell = =...
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- Fall '08