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key_Test_3_CHM_2210_Summer_2013 - Sum me I‘ 1U'5 31 Test...

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Unformatted text preview: Sum me, I‘ 1U) '5 31 Test 3 —-Fa'H-20'12 1. (30 points) Identify the products of these reactions (one bonus point for each fully correct mechanism). wwwéa r7 ,3 WW X” s; W M g a: 5 «Mg 2 m ”13 / ,/ g 5:: 2 Ex M” “If /X <1 :2“ '1“ E M/ 1. NaBH4 2. 1+ H+ OH + f ____’ _ fl / QK \\ MnSK $ m “A » ”mew/{W l~ 49mm V» ‘ _ y, . 03 (1017/91 fl/‘i‘fio’n g Q ff 32%: g; ,,»’s ,1)“ if” f ,/ Na+ “WM Name: £1} €E§Za£fh2b\g»1\flj\/Upfl2 fix {2 «memw \ 2. (25 points) Consider the following reaction. a) Suggest mechanisms for the formation of the products. Some products may come from other products. Blank page follows. SCRATCH PAPER FOR QUESTION 2 ‘ 3. (15 points) How would you do the following conversion? Any reactions required to do this are in question 1 on the test!(More than one step will be required). 0 (T CI . If (/9 f” f f 'R/ q 'i l a 9 { / g, {i O O ’ /\/ w—M‘ {2 t/ x t 2 l , \\ '\ ”J (a (9H {4 3 <4! \4 X [J x) MMMjif’ \ \‘\\< 7 , L/il [MW/ \K {1 ( \‘9 r K _/ 4. (15 points) The following reactions give two different products. Show the mechanisms leading to their formation. H3CO OH (9 o CH3f)H & H 5. (15 points) Identify compounds or reagents A, B, C, D and E. i E z rrrrr (A: O A 1. NaBH4 ____+ 2. H+ A A\ + c I m—CPBA E l/\ 1. MgBr 2 H+ OH x E v X E i? 2k I I W” C O 3 WAX f K E; J i ‘\ Mfg/1" 2/” ...
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