Q1_Wi03 - Provide all proton transfer steps Cl S Cl O OH S...

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NU, Winter 2003 2 1. (20 pts) Complete each of the following reactions by providing the missing starting materials, reagent set(s), or product (only the carbon-containing major product is necessary). If a reaction does not occur, please state so. Your answers should be consistent with any stereochemistry that the reaction may require. i. OH OH H 2 SO 4 100 o C ii. 1) mCPBA (a peracid) 2) EtOH, H 3 0 + , 3) PCC iii. iv. OH 1) KO t Bu, heat 2) BH 3 , THF 3) H 2 O 2 , NaOH v OH 2. (10 pts) Propose a mechanism for the following reaction using the curved arrow formalism.
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Unformatted text preview: Provide all proton transfer steps. Cl S Cl O OH + S O O Cl + + HCl NU, Winter 2003 3 3. (20 pts). Propose a synthesis of the following compound from propene as the only carbon-containing starting material using only the reactions that you learned in Chem 210-1. You may used any necessary inorganic reagents and any sulfur-containing reagent. multistep synthesis Cl...
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This note was uploaded on 06/12/2008 for the course CHEM 210-2 taught by Professor Coddens during the Winter '08 term at Northwestern.

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Q1_Wi03 - Provide all proton transfer steps Cl S Cl O OH S...

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