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Unformatted text preview: v 1 Antistokes scattering + ∆ =-and 2 S branch J 0 Q branch-2 O branch +-∆ =--. Chem 370 Problem Set 7 Spring 2008 Assume that the rotational and vibrational motions of the D 2 molecule are studied by Stokes Raman scattering using visible incident light of wavelength 488.0nm λ = . Sketch assuming the HO-RR model applies the vibrational-rotational Stokes Raman spectrum of a gas of D 2 molecules at T 300K = . In this sketch give the numerical values of the wavenumbers ' ν of scattered light for the Q-branch line, the first S-branch line, and the first O-branch line; and, in a qualitatively correct manner, show the relative Boltzmann intensities of all of the lines. Use Table 13.2 on p. 499. 2...
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- Fall '08
- 300K, Raman scattering, Stokes Raman, 7 1 %, 488.0nm, vibrational-rotational Stokes Raman