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Unformatted text preview: v 1 Antistokes scattering + =-and 2 S branch J 0 Q branch-2 O branch +- =--. Chem 370 Problem Set 7 Spring 2008 Assume that the rotational and vibrational motions of the D 2 molecule are studied by Stokes Raman scattering using visible incident light of wavelength 488.0nm = . Sketch assuming the HO-RR model applies the vibrational-rotational Stokes Raman spectrum of a gas of D 2 molecules at T 300K = . In this sketch give the numerical values of the wavenumbers ' of scattered light for the Q-branch line, the first S-branch line, and the first O-branch line; and, in a qualitatively correct manner, show the relative Boltzmann intensities of all of the lines. Use Table 13.2 on p. 499. 2...
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- Fall '08