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Problem_Set_4

# Problem_Set_4 - CHEM 370 PROBLEM SET 4 SPRING 2008 PROBLEMS...

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CHEM 370 P ROBLEM S ET 4 S PRING 2008 P ROBLEMS FROM M C Q UARRIE AND S IMON From Chapter 4/Some Postulates and General Principles of Quantum Mechanics Problem 4.25 (p. 138) Note the wavefunction ( 29 n x,t Ψ corresponds to a stationary state while the wavefunction ( 29 x,t Ψ corresponds to a non-stationary state . From Math Chapter D/Spherical Coordinates Problem D.1 (p. 153) Problem D.2 (p. 153) Instead of the choices in the problem do only the point ( 29 1 1 1 x,y,z , , 3 3 3 = . Problem D.4 (p. 154) Modify the result for the volume V of a sphere after Eq. (D.3) on p. 149. Problem D.7 (p. 154) Also show that y 2p ψ and 2s ψ given in Problem D.8 are mutually orthogonal. Use spherical polar coordinates and also use the integral formula at the bottom of p. 244. From Chapter 5/The Harmonic Oscillator and the Rigid Rotor: Two Spectroscopic Models Problem 5.20 (p. 183) This was on Problem Set 3. It is repeated here in order to show you an easier way to do it. Using Table 5.3 on p. 170 write the integrand

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• Fall '08
• OldSleepyMan
• Quantum mechanics problem, D/Spherical Coordinates Problem, harmonic oscillator wavefunctions, harmonic oscillator deviates

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Problem_Set_4 - CHEM 370 PROBLEM SET 4 SPRING 2008 PROBLEMS...

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