Chemistry_222_Chapter_3_Problems

Chemistry_222_Chapter_3_Problems - Chemistry 222 Chapter 3:...

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Chemistry 222 Chapter 3: 13, 14, 15, 17, 19, 23, 33, 34, 37, 38, 45, and 65 13. Predict all bond angles about each highlighted carbon atom. C C C CH 2 OH HC C C H 2 C a. b. c. d. C C C C C C OH C Br Br 14. Predict all bond angles about each highlighted carbon atom. a . b . c . d . 15. Draw a structural formula for each compound. a. trans -2-methyl-3-hexene b. 2-methyl-3-hexyne c. 2-methyl-1-butene d. 3-ethyl-3-methyl-1-pentyne
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e. 2,3-dimethyl-2-pentene f. Cis -2-hexene 17. Write the IUPAC name for each unsaturated hydrocarbon. a. CH 2 =CH(CH 2 ) 4 3 b. c. d. (CH 3 ) 2 CHCH=C(CH 3 ) 2 e. 3 (CH 2 ) 5 CC H f. 3 2 C ( C H 3 ) 3 3 3 H 3 C 3 3 19. Explain why each name is incorrect, and then write a correct name. a. 1-methylpropene b. 3-pentene c. 2-methylcyclohexene d. 3,3-dimethylpentene e. 4-hexyne f. 2-isopropyl-2-butene 23. Which of these alkenes shows cis-trans isomerism? For each that does, draw structural formulas for both isomers. a. 1-pentene b. 2-pentene c. 3-ethyl-2-pentene d. 2,3-dimethyl-2-pentene e. 2-methyl-2-pentene
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f. 2,4-dimethyl-2-pentene a.
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This note was uploaded on 07/14/2008 for the course CHEM 222 taught by Professor Mullen during the Spring '08 term at Texas A&M.

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Chemistry_222_Chapter_3_Problems - Chemistry 222 Chapter 3:...

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