122ch11c_002

122ch11c_002 - FW 5 76’.- 5' 79.525" .. . I I. _...

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Unformatted text preview: FW 5 76’.- 5' 79.525" .. . I I. _ ! I 11/1“ 4424-291. .. ' it“ " 6L [5’ _ '... 1" r — 7 . ,l' - ’ . _-. I __/!l d ’5 - .. ' ' ' a: ' " 111111441..- d: e - I (gm-4'; ./ a 1-4" I,” / _- " 4' " ’ /‘/- - f _, ' . _/ ' M? f l...- g A I - (Aim; .J’I ’ - I I 4 ‘ I I I 14 .14...»- /_ m1 . -‘(14-1 _’ {"4 4‘ r“ ‘6) Jill—£1" I‘d-I, If f a . 3/ "‘ l f,IJJ.MJ - 1- ’1’ 1-51 .3 ’54 “A /}L .. x I 4 41ml. _. 1-- _/.-"' 4- 1 1'14. " ' ’1 ’k4. I.” / ’ 4 3’ Q-z’flr 1 A". .1. imam-4" ma am. I “‘ 61 $92!?! 23 I 4’ fleflzfia $4M; .. g a1. {43 9b .2 Sfiéé‘re 5 2% aéavéw 07.42— / I if For 4L- 749 M _ I '_.. flea/€57 43/2252; $214 5 'W fl—‘Aeaéeexg W _ --v In an orthonormal coordinate system, the distance between two points (x1, y1,'z1) and (x2' VQ' 22) is _ x2)2 + (y1 _ Y2): + (Z1 " On Figure 11.4 (b). select a right-handed coordinate system -- and select a bonded pair of ions. One possibility is shown below. In a cubic unit cell. the lengths of all three cell edges are the samefin this case 6.5034.” For Ag”: x = 0.75(6.5o A), y = 0.25(6.50 A), z = 0.25(6.50 A) x =-4.875, y = 1.625, 2 = 1.625 _I-:x=6.5o,y=o,z=o . IThe Ag-I distance is then t/(4.875 — (5.50)2 + (1.625 — 0)2 + (1.625 — 0)2. "—m Ag-I = 1/(1 .625)2 + (1.625):z + (1.625 2 = 2.81 A MK fig 1' [I °f" /'4-/Ld' /Ad 1‘ [A -’ 4-_;;{ 9124/ . . I' ‘9.’ lid/La’ A: .x.‘ 0,; / ’ ' ’ 5.551253: mull- nun-"Immanu- J M- _..(_5¢:_‘6' - ,..v4’fg7odm_________.___....___..‘._________. _ n ____ H. _ 1 m + s W """""" m “z E lag} ...
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122ch11c_002 - FW 5 76’.- 5' 79.525" .. . I I. _...

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