122ch16b - 12 III) M Kala. [#1110141 F”) p0” S+ronfi...

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Unformatted text preview: 12 III) M Kala. [#1110141 F”) p0” S+ronfi e/en‘ro/yfes M 57.050 1” Ally/3 ' [mp/mg I'MiE-e . H/ngéa) —9H*[aj) + 4/412!) Ignore [IV] afar! 7"0 am‘o I‘d/11.347909; 47" £0 Ago/fl) F—‘D‘ [qr/‘25) 'l- fl/Il-Kdi) add f1” from acid [Him < M x»'% IH+J= [#8] f 626:?! 4/0 7'5 : dam/mm sv‘rmg, acid: HQ) #35 HI) FAQ?) #Ciflq) Ham, (mt Hwy) [1) 57"ng 3a$€$ a) fa/uL/e Hydroxide; of Ifl‘klfl Maia/s Cmf/CILQIJ a/z‘ssocz‘afe Mao”) K0” .' 1 0H7Formuu/a urn-1" ()afllllgk , gala”; : a Olly/5.1!. b) 3451b finians fim‘ms Haf f€4¢+ 00- #10 +0 #13) + 240/2) ——> 145(3) + 06,7?) 13 E 54%. [5"], fair?) +P0/n’ 6r 6! 0.0.20 I77 fleafl Sa/n. M1 0 + my) —-> 4/1477) + 49mg) [OH “J = 3- .. 11/ (as) + 36.40/09 w; (can so” @3) 4;. “1,-3.4, +0 N,“ 0; Jaime] P1». Maw, MM, Lag/v M M is # 5/3. 10,}. J7 14 I) weak ’4‘“ ~ 00 I907" camp/9&9 mmee .. __ I‘M/(a (45) F‘- 19%;) + W417?) [ [4/0 "] - Substance Formula K. I /{ -_— a Ami: Icid HC,H,0, 1.7 x in" a Benzoic acid HC,H,02 6.3 x ID" . - [ I?!” J Boric acid H380, 5.9 x 10"“ Cmbonic acid HzCOJ 4.3 x 10—7 HOO,‘ 4.3 x 10‘" O " t _ Cyanic add HCNO 3.5 X [0" flCld" In)?! 947‘)“ _ Formicacid HCHO; 1.1x10" Hydxocyanic Icili HCN 4.9 X ID‘iD Hydmfluuric acid H'F 6.8 x w“ Hydrogen sulfate km HSO.‘ 1.1 x 111'2 + Hydrogen sulfide 14,5 8.9 x in" My HS‘ 12 x 10‘“? H y a Hypochlorous acid new 3.5 x IO" Niimus acid HNo, 4.5 x [0" Oxalic acid H,czo. 5.6 x 10" HCIO.‘ 5.: X It)" Pimsphmic acid mp0. 6.9 x 10“I ' HzPO.‘ 6.2 x m" ' _ HPO"‘ 4.3 x 10*” V -—1 weaker and =9 smaller /{ Wm 12::3» a' Propionic acid HC;H50; 1.3 x u)—5 Pyzuvic acid HC,H,O3 1.4 x 10" 5 jaw /' 2a Sulfurous acid $53;- g: w—I-——.—.—__—_____fl_—__‘___ l! Copyright 0 Heushim MEIHin Cmpany. All rights learned 15 B)_E_zt_2_-' (’a/c. [W] in mm m #stL 5977,10 aw'ees I) Tab/e 4) {ewes/ye flpprox. _ _ mm @— 14" + 4/4; ? me x era/«e Caz/c. 9:- mum. 0-0’0 0 0 f m (0.0/0 —-;r) 9% salve 1%)“ 23“ 1’14 numerai’v/ x + - _ .— 2) [(a = W: 2‘1 ' (0.010— 0.002.!) — V's-x "9 y I Wag? (0.010 —2) = “NW 1 2421*]: Hum-3 3) Sallie For 2 flayed “hf-7'] 04%;? fr: Z 1455mm 2'5 < # of 9;- Fly. 161 (0.0» -— 0.00/73) = ‘f-S'x/o'“ ’ffl'dc. E ror ————"-- z —-= [#*J= [9/1/0'3 l6 16 5) (/se Zuadra he vcarmm/q C) De fee 9" % I’m?“ 1%" xa + M“; xiv-Ox “ “ix/f6 :0 Degree of: lbm‘zall'aa = ___[H7 x ___ 44.5w”) f “’51 a ll] 7 {am} :93»! == —— fie}. roof gives 178,4, [ 19+] 0 a [II/8‘70 A'in -— 5/065»? We $9359 use 0-) raw‘ 7:: [H*J= M X/o"3fl7 17 o D) Mien cam Me a $Sflmy99L/M Ebbing cmmm CHan'mv I Fouth Edition I g b e e ?. Figure 16.? Variation 0! percent ionization of a weak acid with concentration ’ éed era [70 5 Ala [9330 5 M -3. 4 l l‘ ‘ 3 Tia/n error xs .... 570 E ' E _ § 2 Si 1 0 0.02 0.04 0.06 0.08 0.10 Concemralion of nicotinic acid (M) Wing“ e: leuE'hlon Mimi“ Company MI r131", «s‘nnl. 18 $7M I)th are com. 0F a.” was . , 7 More film 1 acidic lfdroéen (WI/3W" M 60”? 9/” m: leg/Dd" (implied/e fer ma/eca/e 3 93m] in 5' MW: hem? __ “glow-5e jam-247,72” I a.) SIM 6? m. asswfi‘hs + _ 01/5? Par/7‘ Ma‘s :2 "‘ 3 ' [/3 Pd, f/ + Ill/90., K“ XIX/0‘ * /éii_>> [(41 >> [(43 Ila/’07 e-H Mfli‘ &a=6.2x/o-°' - 493$”? 4// H" x's HM:- ;‘-‘-‘ H++ P0: £3‘I‘V-RX A9143 I‘M,‘?a+ia-n Sfranier - Prodqde/ I.” .4 . . , ' 74¢ :‘ 7" sf m‘fz‘ ,nt/ .b—aMlssfr .5F5’m, é 6'4 m I “9” HM 3 reduced M and 31%,). g . 'f' _ I Eager “I? remove II From __ like wise M and filer Molar-30d mo/eca/e flaw; farm a. nega'h've f0?! . b) Sen,» hue 4 fine! [H’JHAm'] .——$ + '- HJPqu' H '1" 42/90:; in”. 6.0 0 o u-X. +1 +1 83 6.0—2 2: X x =[H*]=[6$Pd,']= 0.31M? 3.5' 70 error [av/my) [H3P0‘I] '7' I)? Ham; :2 A!" + My” 6:; if! :2 8321’. 02,45 ail-Hf 1’ + .1— fi‘fiffiffih 63"” (“Egg/W]: 6.2 “0.8 [yppq'J-1 6 {ht/0- : /é.2 60 Find, if 20 21 121’) Weak Bases fl) flmMe: )9 Base accepfs 6?- ” * from #10 firm/ad”; 0/1" :fl/fl3 I? = 26/ -¢' C 7m?” _ _ + /+° . rx 4/035 00* f0 0 5W? e ’0" gubshv‘ai‘ec/ Mam/a mg, (a5) + mm a—a- M4725) + 4M7) MW} e_ 7% MW W K _.' [IV/{efjffllij ‘ ' Z 4’65 7 [HM] k [you]: [(5 = [’ijo”? 4/ [ 4'7 [é Cfl/VIZ’ Meflgé/Mimf &z>e —Iam'i'a HM [on 5M Kb = 6’. 4 x xo' 5' weaker base =:> Smaller Kb 39.1 n =4“de augmepfiqlow augmelfixmpfifl auyzmpifl 91111112151113 augwelflquyg GUIIIUV EEHOLLILLIV ul—nmmfi' I—Ip-n._,—n.—.—.—np_n._ F O h W Ch;- A—uu induce ungm nu] aaumsqng Blnuuog mm!” €91W1_ Elfinufl D661 9 W3 mu. ‘AXLSD‘EII—D 'mmmo Wm 22 I) 5x1 : 71¢ p/r’ of a amp/77 0/34/53 soén. if M 3/- 60/1496 is 1% .7 amaze? + M) —<-—* (Mam) + or K = [C/éd’fi’sqfflllj b I [5”3’Vlfi3 P0” = [019'] = [ang -- [ta/W; 3 =- k5 23 WW . .mMa‘al/Base yaw/g, , M, Kb)be #63!ng Fill" 7L cal/30a" fl = Hm“ _ We: 4% M = 46m 6 #0; ,‘5 cam-a afe 62:59 A/ z .0 _1 I? z a 3 07C 0. ifemé acid - a / “0 J /D a 1 cal/367‘s) * 41040 :3" A’Glééfag) +0112?) Kb = 576 WWW fit/anger Let“ er find/er 14m! => K: => [We 3 H0719” Large ’ fma/M‘ 96256 a => Mb _ 24 VII) fie/m‘fimfil‘ 5‘? We” «a q. K” ' éenéraé fluid? mm :2 AI?) + (20'? I: .2 m2 Keg/Vs) m be MM! as) a! 65) K“ #9 give a. 3"] rx. [2541.) HM ao‘zag) + yam) Htiaawwiap Kb - "K3 is frat/ad" m“ K, «a K; . {flzlf'lexaszB} flax/a) :2 H*@3)+0#743) Kw { K, -x «a = «3‘ } - *1! 'J ' 35 - WWW] “flip-‘3“) ' = [m [ox/7 Ka 'kb = kw 25 m1 For taujajm‘e dfld— base pair I) £2: 1 .' WM is W (a For #610???» 1%, = £3xm'7 For 530“ 43g are He [’Ka. 9" [’15 ...
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This note was uploaded on 07/17/2008 for the course CHEM 122 taught by Professor Zellmer during the Summer '07 term at Ohio State.

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122ch16b - 12 III) M Kala. [#1110141 F”) p0” S+ronfi...

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