HW8 - Chem 476 HW 8 Due Nov 2 2007"Catalytic Strategies...

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Chem 476 HW 8 Due Nov 2, 2007 “Catalytic Strategies” Name:________________________ Please complete all questions. Do your work on additional sheets of paper and staple to the back of this sheet. Do not put your answers on this page. You may work with your classmates on this and all homework assignments. I will grade the same three questions for all students and post the answers to the questions after they are due. I.) Problems from the textbook and supplement (do not hand in). Answers are in the textbook (short answers) and supplement (full answers to text AND supplement), but work through on your own first. : Text: 9.1-13 (Most are short answer) Supp: 9.1, 2, 4-6, 9, 10, 15 II.) Additional Problems to hand in : 1.) (a) Sketch an S1 pocket that might cleave a peptide specifically after acidic residues. (b) after alanine and glycine. 2.) Offer two explanations as to why the catalytic triad triple mutant in Figure 9.16 still reacts 1000-fold faster than the uncatalyzed reaction. Your answer should be explained at the
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HW8 - Chem 476 HW 8 Due Nov 2 2007"Catalytic Strategies...

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