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bmb428_problemset20

bmb428_problemset20 - BMB428 Physical Chemistry with...

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BMB428 Dr. Song Tan Physical Chemistry with Biological Applications Fall 2007 1 Problem Set 20: Overview of Kinetics, Zero Order Reactions Due Nov 13, 2007 1. Problem 9.1 (p. 356): Write the rates for the following reactions in terms of the disappearance of reactants and appearance of products: (a) 3O 2 2O 3 (b) C 2 H 6 C 2 H 4 + H 2 (c) ClO - + Br - BrO - + Cl - (d) (CH 3 ) 3 CCl + H 2 O (CH 3 ) 3 COH + H + + Cl - (e) 2AsH 3 2As + 3H 2 2. Problem 9.3 (p. 356) What are the units of the rate constant for a third order reaction? 3. Many reactions show “zero order” behavior under certain conditions. Consider the following equation for the reaction of an enzyme:
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