bmb428_problemset10

bmb428_problemset10 - BMB428 Physical Chemistry with...

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BMB428 Dr. Song Tan Physical Chemistry with Biological Applications Fall 2007 1 Problem Set 10: Review Due Oct 2, 2007 1. Define an open, closed, adiabatic and isolated system by whether heat, work and energy can be exchanged with the surroundings: system exchange of heat? exchange of work? exchange of energy? exchange of matter? open closed adiabatic isolated (fill each box with "yes" or "no") 2. State whether the following properties are intensive properties. Write the units for the properties in the appropriate column: property intensive property? units temperature volume heat capacity Gibb's free energy enthalpy
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BMB428 Dr. Song Tan Physical Chemistry with Biological Applications Fall 2007 2 3. V is a function that depends on only r and h, i.e., V = V(r, h). The total derivative of V is given by: dV rhdr r dh =+ 2 2 ππ (a) Prove that V is a property (use Euler's criterion). (b) Determine V as a function of r and h. (c) What physical property does V describe, and of what geometric object?
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bmb428_problemset10 - BMB428 Physical Chemistry with...

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