L37_TransMetals4

L37_TransMetals4 - 85-100: A 26 (10 exams in 90-97...

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Unformatted text preview: 85-100: A 26 (10 exams in 90-97 range!)75-84: B 2065-74: C 20 56-64: D 150-55: F 3 Tornado demo: Hg(NO3)2+ KI Hg2+(aq) + 2I-(aq)<-> HgI2(s) Ksp=[Hg2+][I-]2=10-4HgI2(s) + 2I-(aq) <-> HgI42-(aq) 80][224IHgIKNa2[HgI4]: sodium tetra-iodo-mercurate(II)Isomers: same composition but different structureIsomersStructural isomersStereoisomersCoordinationisomersLinkage isomersgeometricisomersopticalisomers[Cr(NH3)5Cl]SO4and [Cr(NH3)5SO4]Clare coordination isomers[Cr(NH3)5Cl]SO4: precipitates BaSO4, but does not AgClpentaamminechlorochromium (III) sulfate[Cr(NH3)5SO4]Cl : precipitates AgCl, but does not BaSO4pentaamminesulfatochromium (III) chlorideStructural isomersCoordination isomers:http://www.chem.purdue.edu/gchelp/cchem/coordi2.html[Co(NH3)4(NO2)Cl]Cl and [Co(NH3)4(ONO)Cl]Cl arelinkage isomers[Co(NH3)4(NO2)Cl]Cl yellowtetraamminechloronitrocobalt (II) chloride[Co(NH3)4(ONO)Cl]Cl redtetraamminechloronitritocobalt (II) chlorideLinkage isomers:http://www.chem.purdue.edu/gchelp/cchem/linki2.htmlStereoisomers...
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L37_TransMetals4 - 85-100: A 26 (10 exams in 90-97...

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