L34_TransMetals1

L34_TransMetals1 - Chapter 8 Transition Metals and...

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Chapter 8 Transition Metals and Coordination Chemistry Chemistry of the Transition Metals The Formation of Coordination Complexes Structures of Coordination Complexes Crystal Field Theory and Magnetic Properties The Spectrochemical Series and Ligand Field Theory Isomerism Review Atomic Structure and Molecular Orbitals (Chapters 5-6)
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Transition metals
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Transition metals: Filling d- and f-orbitals
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Transition metals - filling d - and f -orbitals, partially filled shells - can accept and donate electrons - many oxidation states -> tunable chemistry Mn: +2, +3, +4, +7 V: +2, +3, +4, +5 Fe: +2, +3 Cu: +1, +2 - catalysis (Pt, Ru, Cr, V) - added to modify properties of materials (e.g., steel) - materials (e.g., titanium utensils for mountaineering, bikes, etc) - important bio-molecules (enzymes, hemoglobin, vitamins)
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Available Electronic Shells and Subshells and Their Energies Energy 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p
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Electronic Configurations of Many-Electron Atoms
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This note was uploaded on 07/22/2008 for the course CHEM 115b taught by Professor Reisler during the Spring '08 term at USC.

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L34_TransMetals1 - Chapter 8 Transition Metals and...

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