BDEs and HF data - 1.9-5.2-12.9* 27* 32.4 216.5 12.0 -30.2...

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Heats of Formation H F Cl Br I OH NH2 CH3 CH3CH2 (CH3)2CH (CH3)3C H2C=CHCH2 PhCH2 52.1 19.0 29.0 26.7 25.5 9.3 45.5 35.1 28.4 22.0 11.0 40.9 49.5 34.7 -59.5 -54.4 -50.9 -45.1 -32.8 27.1 33.3 34.3 28.7 15.2 29.8 26.9 H 52.1 0.0 -65.3 -22.1 -8.7 6.3 -57.8 -11.0 -17.9 -20.0 -25.0 -32.1 4.9 12.0 365.7 0.0 -65.3 -22.1 -8.7 6.3 -57.8 -11.0 -17.9 -20.0 -25.0 -32.1 4.9 12.0 CH3 35.1 -17.9 -56.0 -20.0 -8.2 3.4 -48.0 -5.5 -20.0 -25.0 -32.1 -40.1 -0.2 7.1 262.0 -17.9 -56.0 -20.0 -8.2 3.4 -48.0 -5.5 -20.0 -25.0 -32.1 -40.1 -0.2 7.1 CH3CH2 28.4 -20.0 -66.0 -26.8 -15.2 -1.7 -56.2 -13.0 -25.0 -30.4 -36.7 -44.4 -5.3 1.9 215.6 -20.0 -66.0 -26.8 -15.2 -1.7 -56.2 -13.0 -25.0 -30.4 -36.7 -44.4 -5.3 1.9 (CH3)2CH 22.0 -25.0 -70.1 -34.7 -22.9 -9.5 -65.2 -20.0 -32.1 -36.7 -42.5 -49.0 -11.8 -5.2 191.5 -25.0 -70.1 -34.7 -22.9 -9.5 -65.2 -20.0 -32.1 -36.7 -42.5 -49.0 -11.8 -5.2 (CH3)3C 11.0 -32.1 -43.0 -31.6 -17.2 -74.7 -28.8 -40.1 -44.4 -49.0 -54.0 -20.0 -12.9* 165.5 -32.1 -43.0 -31.6 -17.2 -74.7 -28.8 -40.1 -44.4 -49.0 -54.0 -20.0 -12.9* H2C=CHCH2 40.9 4.9 -1.3 11.4 23.8 -29.6 -0.2 -5.3 -11.8 -20.0 20.4 27* 229.5 4.9 -1.3 11.4 23.8 -29.6 -0.2 -5.3 -11.8 -20.0 20.4 27* PhCH2 49.5 12.0 -30.2 4.5 20.0 30.4 -22.6 21.0 7.1
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Unformatted text preview: 1.9-5.2-12.9* 27* 32.4 216.5 12.0 -30.2 4.5 20.0 30.4-22.6 21.0 7.1 1.9-5.2-12.9* 27* 32.4 Italics = values from Ab Initio G3 theory Bond Dissociation Enthalpies H F Cl Br I OH NH2 CH3 52.1 19.0 29.0 26.7 25.5 9.3 45.5 35.1 34.7-59.5-54.4-50.9-45.1-32.8 27.1 33.3 H 52.1 104.2 136.4 103.2 87.5 71.3 119.2 108.6 105.1 365.7 400.4 371.5 333.4 323.5 314.3 390.7 403.8 416.9 CH3 35.1 105.1 110.1 84.1 70.0 57.2 92.4 86.1 90.2 262.0 314.6 258.5 227.6 219.3 213.5 277.2 294.6 315.3 CH3CH2 28.4 100.5 113.4 84.2 70.3 55.6 93.9 86.9 88.5 215.6 270.3 222.1 188.0 179.9 172.2 239.0 255.7 273.9 (CH3)2CH 22.0 99.1 111.1 85.7 71.6 57.0 96.5 87.5 89.2 192.0 251.2 202.1 171.8 163.5 155.9 223.9 238.6 256.9 (CH3)3C 11.0 95.2 83.0 69.3 53.7 95.0 85.3 86.2 165.5 232.3 154.1 146.2 137.6 207.4 221.4 238.9 H2C=CHCH2 40.9 88.1 71.2 56.2 42.6 79.8 76.2 229.5 259.3 176.4 167.2 160.6 226.3 263.0 PhCH2 49.5 89.6 61.2 74.0 56.2 44.6 81.4 74.0 77.5 216.5 239.2-17.3 157.6 145.6 141.0 206.3 222.6 242.7...
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This note was uploaded on 07/25/2008 for the course CEM 850 taught by Professor Borhan during the Fall '05 term at Michigan State University.

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