classes_fall07_30BID19_SummerC2007-final

Classes_fall07_30BID - Manashi Chatterjee Ph.D Chem 30B Summer C 2007 Last Name First Name MI Student ID Number Signature Name of your TA

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Manashi Chatterjee, Ph.D. Chem 30B – Summer C 2007 Last Name Student ID Number : First MI Name of your TA: (Please Circle) Rebecca / Eric / Jesus Total: /100 Discussion Section - Day : Time: Chem 30 B Summer C 2007 Final (180 mins) Friday September 14, 2007 DO NOT OPEN THIS EXAM UNTIL INSTRUCTED TO DO SO Signature He Ne Ar Kr Xe F Cl Br I O S Se Te N P As Sb C Si Ge Sn B Al Ga In H Be Mg Ca Sr 1.5 1.2 1.0 1.0 1.5 1.8 2.1 2.5 3.0 2.8 2.4 2.0 1.8 1.6 1.7 1.8 1.9 2.1 2.5 1
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Manashi Chatterjee, Ph.D. Chem 30B – Summer C 2007 Page Point Score 3 4 5 15 15 15 14 6 7 8 9 14 14 Sub-Total 100 13 Page Point 10 11 12 10 10 16 13 14 15 16 19 5 10 20 9 9 17 18 6 5 Total 200 2
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Manashi Chatterjee, Ph.D. Chem 30B – Summer C 2007 1. (15 points) Predict the major product(s) of the following reactions showing stereochemistry wherever appropriate. If no reaction is expected say no reaction. O + NH 2 N H H 2 N O 1. 2. Ph CH 3 O + O 2 N NO 2 2 O 1. CH 3 2 2. mild H + 3. H 2 /Pd/C B B 4. A O O CHO H 2 O, HCl 3
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Manashi Chatterjee, Ph.D. Chem 30B – Summer C 2007 2. (15 points) Predict the major product(s) of the following reactions showing stereochemistry wherever appropriate. If no reaction is expected say no reaction. 4
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Manashi Chatterjee, Ph.D. Chem 30B – Summer C 2007 COOH OCH 3 + NaHCO 3(aq) 1. 2. O OH 3 Zn/ (Hg) HCl 3. CH 2 OH K 2 Cr 2 O 7 ,H 2 SO 4 H 2 O, acetone 4. O 1. CH 3 MgBr, ether 2. NH 4 + Cl - (aq) 1. conc H 2 SO 4 , Δ 2. RCO 3 H 3. NaN 3 ,DMF B A B 3. (15 points) Predict the major product(s) of the following reactions showing stereochemistry wherever appropriate. If no reaction is expected say no reaction.
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This note was uploaded on 03/12/2008 for the course CHEM 30B taught by Professor Rubin during the Spring '05 term at UCLA.

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Classes_fall07_30BID - Manashi Chatterjee Ph.D Chem 30B Summer C 2007 Last Name First Name MI Student ID Number Signature Name of your TA

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