Final.InformationPage.2008

Final.InformationPage.2008 - CONSTANTS R = 8.3145 J mol1 K1...

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CONSTANTS CONVERSION FACTORS R = 8.3145 J mol –1 K –1 C = 3 x 10 8 m/s 1 atm = 760 torr R = 0.08206 L atm mol –1 K –1 h = 6.626 x 10 –34 J s 1 A = 1 C / sec N A = 6.022 x10 23 atoms/mol 1 V = 1 J / C F = 96,485 e mol C 1 L atm = 101.3 J EQUATIONS E = E o F n T R ln Q zero order: [A] = – k t + [A] o k 2 [A] t o 1/2 = E = E o n 0.0257 ln Q at 25 o C first order: ln [A] = – k t + ln [A] o k 0.693 t 1/2 = E = E o n 0.0592 log Q at 25 o C second order: o [A] 1 k t [A] 1 + = o 1/2 [A] k 1 t = K ln F n T R E o = t F n I = Δ G = Δ H T Δ S Δ G = – nFE k = A e –E a / RT Δ G o = Δ H o T Δ S o Δ G o = – nFE o A ln T 1 R E k ln a + = Δ G o = – RT ln K Δ G = Δ G o + RT ln Q = 2 1 a 1 2 T 1 T 1 R E k k ln Δ E = q + w Δ S = q rev /T Δ S = nRln(V 2 /V 1 ) w = – P
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This note was uploaded on 08/06/2008 for the course CHEM 1BL taught by Professor Davis during the Spring '08 term at UCSB.

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