Problem_Set_2_answer_key - CHM 201 Elements of Organic...

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CHM 201 Elements of Organic Chemistry Spring 2007 Problem Set 2 Due Date: May 8, 2007 at 1:00 pm Name_______ answer key _______ Bronco ID No._____________________ Directions Answer each question in the spaces provided. You may use the back of each sheet to continue to answer questions if necessary. Do not attach notebook paper or any other type of paper in the packet. Answer each question legibly. If your answers are illegible, it will not be graded. If question involves calculations, show all work, and provide answers in correct significant digits.
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1) For the following, (a) identify the type of reaction (substitution, elimination or addition) and (b) predict the product(s). Br Br Br Cl + Br 2 h ν a) b) + h ν Cl 2 + + + HBr Substitution Reaction + HCl Substitution Reaction OH c) H 2 SO 4 + + H 2 O Elimination Reaction (Dehydration) OH d) H 2 SO 4 + H 2 O Elimination Reaction (Dehydration) Cl Cl 2 NaNH 2 e) Elimination Reaction 2
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Br Br 2 NaNH 2 f) Elimination Reaction + Cl KOH g) h) Br KOH + 3
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2) For the following reaction, show the full mechanism for each product observed. Label each step of the mechanism.
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