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Problem_Set_3 - Explain your choice Write the complete...

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CHM 201 Elements of Organic Chemistry Spring 2007 Problem Set 3 Due Date: May 15, 2007 at 1:00 pm Name____________________________ Bronco ID No._____________________ Directions Answer each question in the spaces provided. You may use the back of each sheet to continue to answer questions if necessary. Do not attach notebook paper or any other type of paper in the packet. Answer each question legibly. If your answers are illegible, it will not be graded. If question involves calculations, show all work, and provide answers in correct significant digits.
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Spring 2007 Name___________________ 1) Predict the product(s) for the following reactions. a) h ν + Br 2 b) Cl Cl 2 NaNH 2 c) Cl KOH d) OH H 2 SO 4 e) KMnO 4 2 2
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Spring 2007 Name___________________ f) HCl g) Cl 2 h) H 2 O i) HBr j) 2 HCl k) + H 2 O H 2 SO 4 HgSO 4 3
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Spring 2007 Name___________________ l) Br 2 m) 2 KMnO 4 4 H 2 O 3 n) + O 3 H 2 O Zn o) 2 HI p) Br 2 q) Br Br 2 NaNH 2 4
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Spring 2007 Name___________________ 2) The hydration of 1-methylpentene gives two products as shown in the following reaction. Which one of the products formed is the major product?
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Unformatted text preview: Explain your choice. Write the complete mechanism to support your choice by providing any intermediates that may exist. Show correct arrow pushing for full credit. H OH OH H H 2 O H 2 SO 4 + 5 Spring 2007 Name___________________ 3) For the following conjugate diene system, predict the products AND provide a COMPLETE mechanism for the formation of each product observed. You must show complete arrow pushing for full credit. Br 2 + ???? 6 Spring 2007 Name___________________ 4) Predict the product(s) for the following reactions: a) OH Cl AlCl 3 b) N HNO 3 c) OH CO 2 H HNO 3 d) CO 2 H NO 2 H 2 SO 4 e) NHCH 2 CH 2 CH 3 CHO Cl 2 FeCl 3 this is an aldehyde 7 Spring 2007 Name___________________ 5) For the following conjugate diene system, predict the products AND provide a COMPLETE mechanism for the formation of each product observed. You must show complete arrow pushing for full credit. Br 2 + ???? 8...
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