Problem_Set_4 - Show complete arrow pushing and any...

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CHM 201 Elements of Organic Chemistry Spring 2007 Problem Set 4 Due Date: May 31, 2007 at 1:00 pm Name____________________________ Bronco ID No._____________________ Directions Answer each question in the spaces provided. You may use the back of each sheet to continue to answer questions if necessary. Do not attach notebook paper or any other type of paper in the packet. Answer each question legibly. If your answers are illegible, it will not be graded. If question involves calculations, show all work, and provide answers in correct significant digits.
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Spring 2007 CHM 201 1) Predict the product(s) for the following reactions: a) O H 2 Zn b) O LiAlH 4 H 2 O H + c) OH O OH + H + d) O Cl + e) OH PCC 2
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Spring 2007 CHM 201 f) O MgBr + H 2 O H + g) H O 2 2) -H 2 0 1) HO - h) O NH 2 1) LiAlH 4 2) H 2 O i) O + CH 3 CH 2 CH 2 OH H + j) O Ag(NH 3 ) 2 OH 3
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Spring 2007 CHM 201 2) Write a FULL AND COMPLETE mechanism for the products observed in problem 1i. Show complete arrow pushing and any intermediates and/or resonance structures that may exist. Only complete mechanisms will be given full credit. 4
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Spring 2007 CHM 201 3) Write a FULL AND COMPLETE mechanism for the products observed in problem 1g.
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Unformatted text preview: Show complete arrow pushing and any intermediates and/or resonance structures that may exist. Only complete mechanisms will be given full credit. 5 Spring 2007 CHM 201 4) Give an R or S configuration for each of the following molecules in the box provided. Show your work by assigning priorities and showing the direction of rotation in which you chose. If the molecule does not have any stereocenters, write achiral in the box. O H CF 3 CBr 3 H Br Br OH OH CH 3 SCH 3 MeO CH 3 OH H NH 2 a) b) c) d) e) f) 5) For each of the molecules in question 5, draw its enantiomer. a) b) c) d) e) f) 6 Spring 2007 CHM 201 6) For the following molecules, circle letter that describes the relationship of the two molecules. Br Cl Cl Br Br OH OH Br a. enantiomers b. diastereomers c. same molecule e. unrelated a) b) a. enantiomers b. diastereomers c. same molecule e. unrelated 7...
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This note was uploaded on 03/13/2008 for the course CHM 201 taught by Professor Park during the Spring '07 term at Cal Poly Pomona.

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Problem_Set_4 - Show complete arrow pushing and any...

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