Special_Topic_H

Special_Topic_H - P1: PBU/OVY JWDD052-H P2: PBU/OVY QC:...

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P1: PBU/OVY P2: PBU/OVY QC: PBU/OVY T1: PBU Printer: Hamilton JWDD052-H JWDD052-Solomons-v3 April 23, 2007 13:32 H SPECIAL TOPIC Transition Metal Organometallic Compounds SOLUTIONS TO PROBLEMS H.1 CO OC CO Fe CO OC CO Cyclobutadiene iron tricarbonyl Total number of valence electrons (both s and d electrons) of elemental iron oxidation state of the metal in the complex Total number of valence electrons of iron in the complex d n =- d n = 8 - 0 = 8 = 8 + 3(CO) + cyclobutadiene = 8 + 3(2) + 4 = 18 Cyclopentadienylmanganese tricarbonyl Total number of valence electrons of Mn in complex = 6 + 3(CO) + Cp = 6 + 3(2) + 6 = 18 d n = 7 - 1 = 6 Mn
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Special_Topic_H - P1: PBU/OVY JWDD052-H P2: PBU/OVY QC:...

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