Special_Topic_B

Special_Topic_B - P1: QZI/PBR JWDD052-B P2: PBU...

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P1: QZI/PBR P2: PBU Printer: Hamilton JWDD052-B JWDD052-Solomons-v3 April 30, 2007 11:15 B SPECIAL TOPIC Step-Growth Polymers SOLUTIONS TO PROBLEMS B.1 (a) O 2 cat. HNO 3 cat. OH O O O HO OH + N 2 O + (b) (c) (d) heat - 2 H 2 O 2 NH 3 O O HO OH + NH 4 + NH 4 O O - O O - 350 ° C catalyst 4 H 2 catalyst O O H 2 N NH 2 NC CN H 2 N NH 2 2 HCl 2 NaCN 4 H 2 catalyst O NC CN Cl Cl H 2 N NH 2 Cl 2 H 2 Ni 4 H 2 catalyst 2 NaCN NC CN Cl Cl NC CN H 2 N NH 2 391
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P1: QZI/PBR P2: PBU Printer: Hamilton JWDD052-B JWDD052-Solomons-v3 April 30, 2007 11:15 392 SPECIAL TOPIC B B.2 (a) + B - HO OH + HB - O + OH - O OH OCH 3 RO O O + CH 3 O - + B - + CH 3 O - HB CH 3 OH O OCH 3 OH O - O O OH O O [R = CH 3 or HOCH 2 CH 2 ] HA A - O (b) CH 3 O O O + H CH 3 - CH 3 OH + CH 3 OH OH OH O O OCH 3 OH + OH HO + - OH HO O O OH + OH O O OH O O O CH 3 OH OH + OH HA A - [R = CH 3 or HOCH 2 CH 2 ]
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P1: QZI/PBR P2: PBU Printer: Hamilton JWDD052-B JWDD052-Solomons-v3 April 30, 2007 11:15 SPECIAL TOPIC B 393 B.3 (a) O CH 3 O OCH 3 O HO OH + (b) By high-pressure catalytic hydrogenation B.4 C O O C O O etc OCH 2 CHCH 2 OC O COCH 2 CHCH 2 OC O OH COCH 2 CHCH 2 O
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Special_Topic_B - P1: QZI/PBR JWDD052-B P2: PBU...

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