C357_PPS_23_SubElimAssorted_2007

C357_PPS_23_SubElimA - C357 PPS#23 Substitution/elimination Assorted Page 1 of 6 1 In the boxes for the reaction scheme below draw the required

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C357 PPS#23 Substitution/elimination, Assorted Page 1 of 6 1) In the boxes for the reaction scheme below, draw the required reagents, products, or starting materials (whatever is appropriate). For products, one can assume they are organic products only. Li NH3 (l) H 2 SO 4 H 2 O Na H H Br H 1) O 3 2) (CH 3 ) 2 S +
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P a g e 2 o f 6 2) Propose a reasonable mechanism to account for the formation of the following observed reaction product(s). HO HO Br N Heat HO O O O O OH OH HO 3) Propose a reasonable mechanism to account for the formation of the following observed reaction product(s). Br H NaOH OH H 4) Draw and circle the seven unique carbocation intermediates that could be generated during the course of the following reaction. Br H CH 3 OH Heat Carbocation Intermediates Products
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Page 3 of 6 5) Label (on the line) the following statements as true/false for an S N 2 reaction . _____A) 3 o alkyl halides react faster than 2 o halides. _____B)
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This note was uploaded on 09/28/2008 for the course CHEM 3570 taught by Professor Ganem, b during the Fall '06 term at Cornell University (Engineering School).

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C357_PPS_23_SubElimA - C357 PPS#23 Substitution/elimination Assorted Page 1 of 6 1 In the boxes for the reaction scheme below draw the required

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