conditions_for_chemical_equil - COMHW‘MA {MC CWWZM...

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Unformatted text preview: COMHW‘MA {MC CWWZM ga¢<xiftiflfl'mm , m WW1? (charmed) “5% was . , {WWW CC) Weft: 5A CLQVMECQX .ezfmd; hum Ins c um A. H {*PWflfi‘f ’bemwmhm C63 Et4-*IM%V fw .mmawfi‘w it} WWW A (33 h § V a 3 72m wmmwmmwwmwwm,M: W mm." mvmmmwmxwmmrwWMn/mmmr M a“ WWW mum M....wvw.w m... WWW M “WMWMM um i in ._ A80 2“ gamma :7?in W? Mo + AS *3 O N also :«é _¥ wym‘nmwwmnmmnmmur «mw mm "meg «V mm» m. .0 “WWW “mm”. 1 32.... £3) ;+ 5}» {V O W m‘mwymmwmwwmw.WMW-amwwmwém “mm mw‘w MNAW‘EWWTh «we-me) wwwwxwewémN-wmvfiww‘n mmmw, “Wu.” wwwm/‘LeMAM—VMWLW,‘ WMWWM-mw...wmwwnw.www.“~wmq”w~ , Mm.» ‘mm.a...“Wynummmwwwmwnwaflm 0mm”. m 1mimw...w.wm.w WWW. , .w «WWVWWVWHM. My... ' fl Midge v i ‘ M 2-? a? WU. WMme "—- m_._a,W———~—--w 449;: m. mg: 3' \, OW. ,. Z) .. WM“: -Wmm;-.m.wm:mm “NM.” »...., WW ... mm“ * aimiii‘iaxifjé'1WTWi m " § ” Wm‘Qféff—‘r— S flégfiflflVjfl? fu, _ If? % mag; _ "l ‘ ‘7’ “(F fill"W+"“’é'xg L17 6 . /' x} x /‘ x: , Ii /. (MAM/x, mfiG‘f’fi—Mc, 23 Imfwaéq 91;: am )124. WAR? “Wm flywwqwmmww MW. g/‘}M{:¢€mm f ‘1‘, I r, ._ Wm- ".T‘www )wwmm. V. ,gif'” _, ,,,,,, ,,,,,, m .U /‘%’§5n EATS}th i '“ L, Vfivvx w W “.- GW: 2%“) MKOF , introduction to Combustion Phenomena U) G\ 053 .; / .‘ . f.) :11 4 16 M x \5\ -8 \ \fi 5 10 15 20x10'4 Figure C.4 Equilibrium constants for 17 gas reactions (from Hawkins and Smith, Purdue University Engineering Bulletin, Research Series 108, Volume 33. No. 3, 1949) Following are the reactions and the corresponding numbers, they are shown by, in Table C.2 and Figure C4. 1. so2 + 5-02 303 '9. H20 £13112 + OH 2. %Oz + §N2 NO 10. C02 + H2 ‘_ C0 + H20 3. 2:02 0 1i. co2 + C 2C0 4. §H2 H 12. C02 (:0 + 1302 5. §N2 + gnz NH3 13. 2C + H2 C21112 6. %N2 N 14. H2 «1— CO .,.______ C «1% H20 7. M) W N + 0 15. C + 2H2 ' CH4 8. H20 x H2 + %02 16. C0 + 2H2 x CH3OH 17. C0 + 31112 -—--* CH4 + H20 Now the products C and D at PC and PD and 298 UK; are isothertnally ex- panded to the pressures of 1 atmosphere. The free energy change associated with this isothermal expansion is T 4.1 flenee L116 n 1 atm and 298 °K ...
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conditions_for_chemical_equil - COMHW‘MA {MC CWWZM...

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