2007T1 - CHEM 2535 Test #1: Bruice Chapters 1 3.3 100...

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1 CHEM 2535 Test #1: Bruice Chapters 1 – 3.3 100 points Print Name ___________________________________Signature ___________________________________ Friday, Sept. 21, 2007 Your signature indicates that you abide by the Honor Code at Virginia Tech (www.honorsystem.vt.edu). Models permitted. (18 points) 1 Name by IUPAC: CH 3 CH CH 3 CH 2 CH 2 CH CH 2 CH 3 CH 3 Br CH 3 CH 3 CH 3 CH CH 2 CH CH 3 Cl CH 3 CH 3 CH 2 O CH CH 3 CH 2 CH 3 CH 3 (8 points) 2. Challenging nomenclature. Name the following by IUPAC. CH 3 CH 3 CC Cl CH 3 CH 2 OH CH 3
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2 (8 points) 3. Use the table provided to (a) label SA, SB, WA, WB; (b) give the pKa’s of the acids; (c) determine whether equilibrium lies to the left or right. A pKa table is on the last page. CH 3 CH 2 OH + NH 3 CH 3 CH 2 O - + NH 4 + (4 points) 4. Based on your knowledge of Acid-Base chemistry, which direction will the equilibrium lie? (Draw the appropriate arrow) Note: One of the acids is not listed on the pKa table – use your best approximation, ie, does it look like something else on the table? CH 3 CH 2 OH + HCl + Cl - CH 3 CH 2 O H H (12 points) 5. Intermolecular Forces. Complete the following table by writing your answer in each square. Some squares are already filled in.
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2007T1 - CHEM 2535 Test #1: Bruice Chapters 1 3.3 100...

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