Problem_Set_4_KEY - or 1. LiAlH 4 2. H 3 O + 1. CO 2 2. H 3...

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Problem Set #4: Chapter 20 1. Provide the products and/or the conditions for the following transformations: Br CO 2 H 1. Mg, ether 2. CO 2 3. H 3 O + Cl 1. NaCN 2. LiAlH 4 3. H 3 O + NH 2 I 1. NaCN 2. CH 3 MgBr 3. H 3 O + O Br OH 1. Mg, ether 2. CO 2 3. BH 3 NH 2 O 1. SOCl 2 2. H 3 O + OH O
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KMnO 4 H 3 O + O HO O OH + OH O NaHCO 3 ONa O CN 1. CH 3 CH 2 MgBr 2. H 3 O + O H O Ag 2 O NH 4 OH OH O NH 2 O O 1. SOCl 2 2. PhCH 2 MgBr 3. H 3 O +
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2. Provide a reasonable synthesis for the following molecules using the given starting material and any other carbon contaning compound you need with 2C atoms or less. a. b. OH CO 2 H Br CN MgBr NaCN or H 3 O + heat BH 3
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Unformatted text preview: or 1. LiAlH 4 2. H 3 O + 1. CO 2 2. H 3 O + Mg, ether HBr NaCN OH O PBr 3 Br CN 1. 2. H 3 O + MgBr 3. Provide a name or a structure for the following compounds Cl OH O 7-benzyl-6-methoxy-3-methyl-octane nitrile COOH Br O 2 N o-chloro-benzoic acid O CN 3-bromo-5-nitro-cyclooctane carboxylic acid OH Br O 7-benzyl-4-bromo-nonanoic acid m-bromo-benzonitrile CN Br 4-methoxy-3-nitro-cyclohexane carboxylic acid COOH NO 2 O...
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This note was uploaded on 03/19/2008 for the course CEM 252 taught by Professor Rathke during the Spring '08 term at Michigan State University.

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Problem_Set_4_KEY - or 1. LiAlH 4 2. H 3 O + 1. CO 2 2. H 3...

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