Problem_Set_8_KEY - material and any other carbon contaning...

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Problem Set #8: Chapter 24 1. Provide the products and/or the conditions for the following transformations. O NH 2 NaCNBH 3 NH Br 1. NaN 3 2. H 2 /Pd 1. NaCN 2. H 2 /Pd NH 2 NH 2 NH O 1. LiAlH 4 2. H 2 O NH NH 2 1. CH 3 CH 2 Br (xs) 2. Ag 2 O, H 2 O 3. heat Br NH O O 1. , KOH 2. NaOH, H 2 O NH 2
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Cl O 1. Na N 3 2. H 2 O, heat NH 2 NH 2 O NaOH, Br 2 H 2 O O H NH 3 NaCNBH 3 NH 2 1. HNO 2 , H 2 SO 4 2. KCN 3. CH 3 MgBr O NH 2 H NH 2 NH 2 O Cl N H O
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2. Provide a reasonable synthesis for the following molecules using the given starting
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Unformatted text preview: material and any other carbon contaning compound you need. Br N NH O O 1. , KOH 2. NaOH, H 2 O NH 2 H H O NaCNBH 3 H N Cl O N O 1. LiAlH 4 2. H 3 O + Br N NaN 3 N 3 NH 2 O NaCNBH 3 HN H H O NaCNBH 3 3. Determine the structure of the following compounds based on their 1H-NMR spectra: A. C 7 H 17 N B. C 7 H 9 N 1 2 3 4 5 6 PPM 2 1 2 12 NH 2 1 2 3 4 5 6 7 8 9 PPM 2 2 2 3 N...
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Problem_Set_8_KEY - material and any other carbon contaning...

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