Quiz_2_green - 6 What are the correct conditions for the...

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Quiz #2 (20 points) Name:_______________ CEM252 PID:_________________ Section:______________ Mark your answers in the box below (only answers in the box will be graded) Q1. Q3. Q5. Q7. Q9. Q2. Q4. Q6. Q8. Q10. 1. Which of the following compounds is a secondary alcohol? (2 points) 2. What is the correct name for the following molecule? (2 points) 3. Put the following compounds in order of increasing pK a (2 points) 4. What is the product of the following transformation? (2 points) OH a b c d e OH OH OH OH CH 3 OH OH OH OMe OH NO 2 OH NO 2 O 2 N NO 2 B D C A E a. D < A < E < C < B b. C < A < E < B < D c. A < C < B < D < E d. B < D < E < A < C e. None of the above a b c d 1. OsO 4 , pyr. 2. NaHSO 3 product e OH OH OH OH OH OH a. 3,6-dimethyl-6-benzyl-4-octtanol b. 6-ethyl-3-methyl-6-phenyl-4-heptanol c. 1,3-dimethyl-4-methyl-4-phenyl-3-heptanol d. 3,6-dimethyl-6-phenyl-4-octanol e. 3,6-dimethyl-4-hydroxy-6-phenyl-octane OH
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5. What is the product of the following transformation? (2 points)
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Unformatted text preview: 6. What are the correct conditions for the following transformation? (2 points) 7. What is the product of the following transformation? (2 points) 8. What are the correct conditions for the following transformation? (2 points) 9. What is the product of the following transformation? (2 points) 10. What is the product of the following transformation? (2 points) H O 1. LiAlH 4 2. H 3 O + product a b c d e H O H OH H OH H H HO OH HO OH a. 1. LiAlH 4 ; 2. H 3 O + b. 1. PhMgBr; 2. H 3 O + c. 1. NaBH 4 ; 2. H 3 O + d. 1. CH 3 MgBr; 2. H 3 O + e. 1. CH 3 CH 2 MgBr; 2. H 3 O + O OH ? a b c d e OH POCl 3 pyridine, 0 o C product OH OH OH PCC product a b c d e O H O OH O H O H O TMSCl (Et) 3 N product H O a b c d e OTMS OH H OH OH H OH OTMS H OTMS OTMS Cl O OH ? OH Br a. HBr b. POCl 3 c. SOCl 2 /pyr d. Br 2 / FeBrl 3 e. PBr 3 /pyr...
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This note was uploaded on 03/19/2008 for the course CEM 252 taught by Professor Rathke during the Spring '08 term at Michigan State University.

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Quiz_2_green - 6 What are the correct conditions for the...

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