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Quiz_2_white - 7 What is the product of the following...

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Quiz #2 (20 points) Name:_______________ CEM252 PID:_________________ Section:______________ Mark your answers in the box below (only answers in the box will be graded) Q1. Q3. Q5. Q7. Q9. Q2. Q4. Q6. Q8. Q10. 1. Which of the following compounds is a tertiary alcohol? (2 points) 2. What is the correct name for the following molecule? (2 points) 3. Put the following compounds in order of increasing pK a of the –OH. (2 points) 4. What is the product of the following transformation? (2 points) OH a b c d e OH OH OH OH CH 3 OH OH OH OMe OH NO 2 OH NO 2 O 2 N NO 2 B D C A E a. B < D < E < A < C b. D < A < E < C < B c. A < C < B < D < E d. C < A < E < B < D e. None of the above a b c d 1. Hg(OAc) 2 , H 2 O 2. NaBH 4 product e OH OH OH OH OH OH OH a. 3,6-dimethyl-6-benzyl-4-octanol b. 3,6-dimethyl-6-phenyl-4-octanol c. 1,3-dimethyl-4-methyl-4-phenyl-3-heptanol d. 6-ethyl-3-methyl-6-benzyl-4-heptanol e. 3,6-dimethyl-4-hydroxy-6-phenyl-octane
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5. What is the product of the following transformation? (2 points) 6. What are the correct conditions for the following transformation? (2 points)
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Unformatted text preview: 7. What is the product of the following transformation? (2 points) 8. What are the correct conditions for the following transformation? (2 points) 9. What is the product of the following transformation? (2 points) 10. What is the product of the following transformation? (2 points) H O 1. LiAlH 4 2. H 3 O + product a b c d e H O H OH H OH H H HO OH HO OH O OH ? a. 1. CH 3 CH 2 MgBr; 2. H 3 O + b. 1. PhMgBr; 2. H 3 O + c. 1. NaBH 4 ; 2. H 3 O + d. 1. CH 3 MgBr; 2. H 3 O + e. 1. LiAlH 4 ; 2. H 3 O + a b c d e OH POCl 3 pyridine, 0 o C product HO OH OH CrO 3 H 2 SO 4 , H 2 O product a b c d e O H O OH O OH O H O TMSCl (Et) 3 N product H O a b c d e OTMS OH H OH OH H OH OTMS H OTMS OTMS Cl O OH ? OH Br a. HBr b. POCl 3 c. PBr 3 /pyr d. Br 2 / FeBrl 3 e. SOCl 2 /pyr...
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Quiz_2_white - 7 What is the product of the following...

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