Problem_Set_5

Problem_Set_5 - Br NO 2 Br NO 2 Br NO 2 Br NO 2 NO 2 Br NO...

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Chem 358 Spring 2007 Problem Set #5 Text Problems Chapter 17 : 17. 10, 11, 12, 13, 14, 17, 18 Chapter 18 : 18 .2, 4, 5, 6, 36(c), 38, 39, 40, 42(a), (c), (e), 50, 54(a)-(e), (h), (i), 56(a), (e), (f), (m), 57, 60, 61, 65(a), (b), 66, 68, 70 Additional problems 1. Write down the structure of the product for the reaction shown. Using curved arrow formalism, write a detailed mechanism for the reaction. NBS (1 equiv.) h ! 2. Rank the following in the order (fastest one first) in which they will react with hydroxide ion (HO - ) in nucleophilic aromatic substitution.
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Unformatted text preview: Br NO 2 Br NO 2 Br NO 2 Br NO 2 NO 2 Br NO 2 NO 2 3. Write down the major product in each of the following transformations. Cl Cl O 2 N NO 2 NaOCH 3 CH 3 OH 1. KMnO 4 , -OH, heat 2. H +, H 2 O CH 3 1. (CH 3 ) 2 CHCl, AlCl 3 2. HNO 3 , H 2 SO 4 3. KMnO 4 , -OH, heat 4. H +, H 2 O. 1. KMnO 4 , -OH, heat 2. H +, H 2 O 4. Circle all the isoprene units in each of the following terpenes. CH 3 H 3 C H H H 3 C CH 3 O O O O !-Cadinene H 3 C CH 3 CH 3 HO O O O CH 3 OH O O O H H 3 C O CH 3 O O N O OH O H Taxol...
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This note was uploaded on 04/22/2009 for the course CHEM 3570 taught by Professor Ganem, b during the Fall '06 term at Cornell.

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Problem_Set_5 - Br NO 2 Br NO 2 Br NO 2 Br NO 2 NO 2 Br NO...

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