Problem_Set_10 - Chem 358 Spring 2007 Problem Set 10 These...

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Spring 2007 Problem Set 10 These are repeat from PS #9.: Chapter 22: 22. 40, 49, 68(c), 69, 71(a), (b), 73(a)-(e), (g), (i), (l), 74, 78(e), 79(a), (d)-(i) Additional Problems 1. (This is a repeat question.) Suggest a plausible mechanism to account for each of the following transformations. CO 2 CH 2 CH 3 O Na + - OCH 2 CH 3 , CH 3 CH 2 OH O CO 2 CH 2 CH 3 O 2. (Repeat) Fill in the missing reagents in the reaction sequence shown below. More than one synthetic step may be needed for each transformation. Do this without looking at answers to PS #9. Br Br HO 2 C CO 2 H (b) CH 3 O 2 C CO 2 CH 3 (a) (c) O CO 2 CH 3 O CO 2 CH 3 O CO 2 CH 3 O (d) (e) 3. Provide the reagents necessary to convert cyclohexanone into the indicated products. O O O O O O O O O O OH O OH O O O 4. What reagents ((a)—(e) would be required to carry out the following transformations? H O O O Na + O O CH 3 CH 2 O O (a) (b) (c) (d) (e) 5. Propose a plausible mechanism for the following. O
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This note was uploaded on 04/22/2009 for the course CHEM 3570 taught by Professor Ganem, b during the Fall '06 term at Cornell University (Engineering School).

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Problem_Set_10 - Chem 358 Spring 2007 Problem Set 10 These...

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